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Second-sphere photochemistry and photophysics: Luminescence of the [Pt(bpy)(NH3)2]2+-dibenzo[30]crown-10 adduct

Structure of the cis-cisoid-cis isomer of 2,3,11,12 – tetra – anisyl – 18-crown-6: rel-(2R,3S,11R,12S) – 2,3,11,12 – tetrakis – 4 – methoxypheny l- 1,4,7,10,13,16 – hexaoxa – cyclooctadecane

A 1:1 adduct between the cis-cisoid-cis isomer of 2,3,11,12-tetra-anisyl – 18-crown-6 and borane ammonia, BH3NH3

Structure of the cis-transoid-cis isomer of 2,3,11,12 – tetra-anisy l- 18-crown-6: rel-(2R,3S,11S,12R) – 2,3,11,12-tetrakis – 4-methoxyphenyl – 1,4,7,10,13,16 – hexaoxa – cyclooctadecane

A 1:2 adduct between the cis-transoid-cis isomer of 2,3,11,12 – tetra-anisy l- 18-crown-6 and borane ammonia, BH3NH3

Structure of the trans-cisoid-trans isomer of 2,3,11,12-tetra-anisyl – 18-crown-6: rel-(2R,3R,11S,12S) – 2,3,11,12-tetrakis – 4-methoxyphenyl – 1,4,7,10,13,16 – hexaoxa – cyclooctadecane

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